Acrylonitrile-butadiene-styrene terpolymer,flame retarding
Acrylonitrile-butadiene-styrene terpolymer,flame retarding
CAS: 9003-56-9
Molecular Formula: C45H51N3X2
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Names and Identifiers
| Name | Acrylonitrile-butadiene-styrene terpolymer,flame retarding |
| Synonyms | ABS styrene absresin absresins Abs Resins abscopolymer buta-1,3-diene prop-2-enenitrile acrylonitrile-butadiene-styrenecopolymers Acrylonitrile-butadiene-styreneterpolymer acrylonitrile,polymerwith1,3-butadieneandstyrene Acrylonitrile-butadiene-styrene terpolymer,flame retarding 2-propenenitrile,polymerwith1,3-butadieneandethenylbenzene |
| CAS | 9003-56-9 |
| InChI | InChI=1/C8H8.C4H6.C3H3N/c1-2-8-6-4-3-5-7-8;1-3-4-2;1-2-3-4/h2-7H,1H2;3-4H,1-2H2;2H,1H2 |
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Physico-chemical Properties
| Molecular Formula | C45H51N3X2 |
| Molar Mass | 633.91 |
| Density | 1.05 g/mL at 25 °C |
| Melting Point | 58.54（±0.5）℃ |
| Boling Point | 145.2°C at 760 mmHg |
| Flash Point | 31.1°C |
| Water Solubility | acetone, MEK and DMF: soluble |
| Vapor Presure | 6.21mmHg at 25°C |
| Appearance | Form powder, color natural |
| Use | For the preparation of instruments, electrical, electrical, mechanical and other parts |
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
| Safety Description | S36 - Wear suitable protective clothing. |
| UN IDs | UN 2215 8 / PGIII |
| WGK Germany | 3 |
| RTECS | AT6970000 |
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Upstream Downstream Industry
| Raw Materials | 1,3-BUTADIENE |
| Downstream Products | polyolefine conductive plastics |
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Nature
Open Data Verified Data
ABS resin is amorphous, opaque terpolymer, generally light yellow pellets or beads, it has the advantages of three components, is a tough, hard, material with good rigidity. Acrylonitrile gives ABS resin chemical stability, oil resistance, certain rigidity and hardness; Butadiene improves its toughness, impact and cold resistance; Styrene makes it have good dielectric properties and gloss, and show good processing characteristics. The melting temperature of ABS resin is 190~240 deg C, thermal decomposition temperature> 250 deg C. The product has good dimensional stability, molding shrinkage is small. Has excellent comprehensive physical and mechanical properties, non-toxic, odorless, heat resistance, impact resistance, especially good low temperature impact; Electrical properties, wear resistance, chemical stability; Water resistance, inorganic salts, alkali and acids; insoluble in most alcohols and hydrocarbon solvents, and soluble in aldehydes, ketones, esters and some chlorinated hydrocarbons; Poor weather resistance, flammable, low heat distortion temperature.
Last Update：2024-01-02 23:10:35
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Preparation Method
Open Data Verified Data
There are many industrial production methods for BS resin. At present, the most widely used in the world is still the emulsion method, which can be divided into two categories: emulsion grafting and emulsion grafting blending. The bulk suspension method still has some practical value. This is briefly described as follows.
- the floating liquid grafting method of butadiene (or styrene) in the polymerization kettle, the synthesis of fatty acid potassium soap as emulsifier, organic peroxide as initiator, polybutadiene or styrene-butadiene latex was prepared by emulsion polymerization at 5-20 °c. A certain amount of latex is added to the graft polymerization reactor in the required ratio of styrene, acrylonitrile, emulsifier, initiator (potassium persulfate) and regulator (tertiary mercaptan), the graft polymer latex was obtained by emulsion graft copolymerization at 60-90 ℃ for 6H. The antioxidant is added to the latex, and the ABS resin product is obtained by separating, washing, drying and granulating with salt water or sulfuric acid in the coagulation tank.
- emulsion grafting blending method the PB latex prepared by emulsion grafting method is blended with AS latex prepared from styrene and acrylonitrile, and then washed with condensed water, centrifuged, dried, ABS resin products were obtained by granulation. ABS powder prepared by emulsion graft copolymerization of polybutadiene latex, ABS resin product prepared by blending AS pellets and various additives by suspension polymerization, foreign industrial production is often used in the method.
- Bulk-suspension method polybutadiene (or styrene-butadiene) rubber is first dissolved in styrene and acrylonitrile monomers, and bulk prepolymerization is carried out. When the polymerization conversion rate reaches 20% ~ 40% and the phase transition occurs, it is transferred to a water-containing suspension polymerization kettle for suspension polymerization. After the polymerization reaction is finished, the product is obtained by centrifugal dehydration, washing and drying.
- According to the characteristics of the three monomers in ABS, by adjusting the proportion of each monomer, molecular weight, adding additives, can produce a variety of ABS brands to meet the requirements of different customers. Theoretically, the composition of ABS can vary indefinitely, but is usually in the range of A/B/S = (20 to 30)/(5 to 40)/(40 to 70). For example, by controlling the content (lower), particle size (smaller), AN content and molecular weight (lower) of the rubber phase in ABS, high gloss ABS can be obtained; Increase the rubber content, cold resistant, high impact ABS can be prepared; Improve the melt strength (molecular weight), can be prepared blow molding grade ABS.
Last Update：2022-01-01 11:07:53
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Safety
Open Data Verified Data
resin production raw materials, the skin and mucous membranes of the human body have different degrees of stimulation, can cause skin allergic reactions and inflammation; At the same time also pay attention to the harm of resin dust on the human body, long-term inhalation of high concentrations of resin dust, can cause lung lesions. Most of the resin has a common dangerous characteristics: open flame, high temperature flammable, and oxidant contact has caused the risk of combustion, therefore, the operation of vacuum forming on the processed plate, the operating personnel should improve the operating environment, the operating area and the non-type temperature to 120~170 ℃ as good as the operating area of the conscious drawing, as far as possible automation, sealing, installation of ventilation facilities. Paper plastic bag bag resin production raw materials, the human body leather, 25kg/bag, stored in a cool, ventilated and dry place
Last Update：2022-01-01 11:07:54
Acrylonitrile-butadiene-styrene terpolymer,flame retarding - Molding Process
Open Data Verified Data
ABS resin is an amorphous polymer with good processability. Not only can be used in injection molding, extrusion, calendering, blow molding, vacuum and foaming and other general molding processing methods, can also be used in cold molding processing. But not applicable to compression and transfer molding
Processing, also should not use hot melt method or casting method. Because of the small hygroscopicity of ABS resin, it can be used for molding processing without drying under normal circumstances, and the surface gloss of the product is better if it is processed after drying. During injection molding, the material temperature is controlled at 200~240 ℃, the injection pressure is 50 ~ lOOMPa, and the mold temperature is 40~80 ℃. The molded article can be annealed at 70 °c for 2-4H in an infrared lamp or a blast oven to remove internal stress. During extrusion molding, the temperature of the front part of the cylinder is 170~180 ℃, the temperature of the middle part is 180~220 ℃, the temperature of the head is 180~220 ℃, the temperature of the die is 180~210 ℃, and the ratio of the length to diameter of the screw is 18~20, the compression ratio was 2.5 to 3.0.
ABS plastic can be welded by flame and ABS electrode, or bonded with 10% ABS methyl ethyl ketone solution, and can also be used for drilling, sawing, cutting, turning, milling and other mechanical secondary processing. The surface of the parts is very easy to be plated and printed.
- injection molding.
- extrusion molding.
- for the processed plate by vacuum forming, the forming temperature is 120~170 ℃.
Last Update：2022-01-01 11:07:54
Supplier List
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: +86-18721521379
Email: 18721521379@163.com
Mobile: +86-18721521379
Wechat: 18721521379
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: +86-17505207175
Email: r@reformchem.com
Mobile: +86-17505207175
QQ: 3787852685
Wechat: chemical6666
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Wechat: chemical6666
Product Name: ABS Resins Request for quotation
CAS: 9003-56-9
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589
CAS: 9003-56-9
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589
Spot supply
Product Name: ABS Resins Visit Supplier Webpage Request for quotationCAS: 9003-56-9
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotation
CAS: 9003-56-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
CAS: 9003-56-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Spot supply
Product Name: ABS Resins Visit Supplier Webpage Request for quotationCAS: 9003-56-9
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Product Name: ABS Resins Visit Supplier Webpage Request for quotation
CAS: 9003-56-9
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
CAS: 9003-56-9
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: +86-18721521379
Email: 18721521379@163.com
Mobile: +86-18721521379
Wechat: 18721521379
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: +86-17505207175
Email: r@reformchem.com
Mobile: +86-17505207175
QQ: 3787852685
Wechat: chemical6666
Spot supply
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotationCAS: 9003-56-9
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Wechat: chemical6666
Product Name: ABS Resins Request for quotation
CAS: 9003-56-9
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589
CAS: 9003-56-9
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589
Spot supply
Product Name: ABS Resins Visit Supplier Webpage Request for quotationCAS: 9003-56-9
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Product Name: Acrylonitrile-butadiene-styrene terpolymer,flame retarding Request for quotation
CAS: 9003-56-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
CAS: 9003-56-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Spot supply
Product Name: ABS Resins Visit Supplier Webpage Request for quotationCAS: 9003-56-9
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Product Name: ABS Resins Visit Supplier Webpage Request for quotation
CAS: 9003-56-9
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
CAS: 9003-56-9
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
View History
Acrylonitrile-butadiene-styrene terpolymer,flame retarding
6-甲基吡啶-3-甲基氨基
cis-12-Tetradecenylacetate
4H-Pyrazol-4-one, 3,5-dimethyl-, oxime 1,2-dioxide
5-溴-3-甲基吡嗪-2-醇
5-甲基-2-乙酰基呋喃
Pigment -- Pigment Red 32
10-aminothioxanthene
RuO2·2H2O
6-甲基吡啶-3-甲基氨基
cis-12-Tetradecenylacetate
4H-Pyrazol-4-one, 3,5-dimethyl-, oxime 1,2-dioxide
5-溴-3-甲基吡嗪-2-醇
5-甲基-2-乙酰基呋喃
Pigment -- Pigment Red 32
10-aminothioxanthene
RuO2·2H2O
Raw Materials for Acrylonitrile-butadiene-styrene terpolymer,flame retarding
Downstream Products for Acrylonitrile-butadiene-styrene terpolymer,flame retarding